Ethyl (E)-4-(2-formylphenoxy)but-2-enoate

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(E)-Ethyl 2-benzoyl-4-(naphthalen-2-yl)-4-oxobut-2-enoate

The title compound, C(23)H(18)O(4), is a 1,4-enedione compound which contains a naphthalene ring and a benzene ring. The dihedral angle between the ring systems is 74.9 (2)°. In the crystal, the mol-ecules form π-π stacking inter-actions between naphthalene rings of inversion-related mol-ecules, with an inter-planar spacing of 3.499 (2) Å.

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(E)-Ethyl 2-cyano-3-(2,4-dimeth­oxy­phen­yl)prop-2-enoate

The C=C bond in the title compound, C(14)H(15)NO(4), is in an E configuration. With the exception of the methyl C atoms, the non-H atoms of the mol-ecule all lie approximately on a plane (r.m.s. deviation = 0.096 Å). π-π stacking is observed between parallel benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.7924 (8) Å.

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Ethyl (E)-3-hy­droxy-2-[(4-meth­oxy­styr­yl)­carbamo­yl]but-2-enoate

The title compound, C(16)H(19)NO(5), which was synthesized from p-meth-oxy-cinnamic acid, has intra-molecular O-H⋯O and N-H⋯O hydrogen-bonding inter-actions. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum ring centroid-centroid separation = 3.790 (1) Å].

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Ethyl 3-benzoyl-2-hydroxy­prop-2-enoate

In the title compound, C(12)H(12)O(4), the dihedral angle between the plane through the phenyl ring and the mean plane of the side chain is approximately 14°. The mol-ecules, which contain an intra-molecular O-H⋯O hydrogen bond, are linked end-to-end by weak C-H⋯O inter-molecular hydrogen-bonding contacts, forming infinite one-dimensional chain systems in the crystal structure.

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Crystal structure of ethyl (E)-4-(4-chlorophen­yl)-4-meth­oxy-2-oxobut-3-enoate

In the title compound, C13H13ClO4, the dihedral angle between the chloro-benezene ring and the least-squares plane through the 4-meth-oxy-2-oxobut-3-enoate ethyl ester residue (r.m.s. deviation = 0.0975 Å) is 54.10 (5)°. In the crystal, mol-ecules are connected by meth-oxy-ketone and benzene-carboxyl-ate carbonyl C-H⋯O inter-actions, generating a supra-molecular layer in the ac plane.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2005

ISSN: 1600-5368

DOI: 10.1107/s1600536805013164